TYM2018
Tanaka, H., Yagasaki, T. & Matsumoto, M.
On the phase behaviors of hydrocarbon and noble gas clathrate hydrates: Dissociation pressures, phase diagram, occupancies, and equilibrium with aqueous solution.
J. Chem. Phys. 149, 074502 (2018). (AIP Featured article, Scilight)
http://doi.org/10.1063/1.5044568
統計力学理論に基き、任意の温度圧力においてガスハイドレートの組成比がとりうる値の範囲を、シミュレーションを行わないで正確に推定する方法を述べました。これまでにない精度で、ガスハイドレートの相図を描けるようになりました。
We have described a method to accurately estimate the range of possible composition ratios at arbitrary temperature pressure, without simulation, based on statistical mechanics theory.
https://aip.scitation.org/na101/home/literatum/publisher/aip/journals/content/sci/2018/sci.2018.2018.issue-33/1.5051832/20180816/images/large/1.5051832.figures.online.f1.jpeg
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